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Alexa Rank for Temario ifses eir is 10276. More about Temario ifses eir at Temario ifses eir.pdf3:Photophysics of organic molecules has been the subject of numerous review articles in the past. Recent attention in this area has focused on transition metal complexes because of their potential utility as electro-optic and charge transport materials.
Dias et al., Adv. Mater. 6, No. 9 (1994) and Roesky et al., Chem. Rev., 1993, 93, 733 have reviewed the wealth of information and state of the art regarding metal-containing macrocycles and their photophysics. Roesky et al. also point out that the design, synthesis and characterization of the structural isomers of 2,2′-bipyridyl is an area of intense study, since the synthetic accessibility of these complexes can vary significantly. A review by Hewitt, Synth. Met., 1993, 69, 191, and references cited therein, describes the structural diversity of the metal-polypyridyl macrocycles. The stability of these complexes under different conditions, especially in the presence of light, is also an area of interest, and a review by Folmer et al., Chem. Rev. 1994, 94, 927, contains information on strategies for synthesizing these complexes in air.
Although the synthesis of the metal-containing macrocycles is relatively straightforward, the syntheses of organic-metal macrocycles are a relatively new area of chemistry. The macrocycles, which are referred to as “Monomer-Br.TM.- or “Monomer-Mn.TM.-containing macrocycles”, are metal complexes which contain a metal ion and an organic ligand in the form of a macrocycle. The macromolecular nature of the macrocycles renders them highly insoluble in most solvents and thermally unstable, especially in air. As a consequence, research efforts have focused on elucidating the synthetic conditions, i.e., solvents, to
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